Reactivity of hydride bridges in a high-spin [Fe3(μ-H)3]3+ cluster: reversible H2/CO exchange and Fe–H/B–F bond metathesis† †Electronic supplementary information (ESI) available: Experimental and theoretical procedures and figures, crystallographic details, and theoretical structures. CCDC 1523783 and 1523784. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c6sc05583d Click here for additional data file. Click here for additional data file.
نویسندگان
چکیده
Reactivity of hydride bridges in a high-spin [Fe3(μ-H)3] cluster: reversible H2/CO exchange and Fe–H/B–F bond metathesis Kevin J. Anderton, Brian J. Knight, Arnold L. Rheingold, Khalil A. Abboud, Ricardo García-Serres and Leslie J. Murray* a Center for Catalysis and Department of Chemistry, University of Florida, Gainesville, Florida 32611, United States c Department of Chemistry and Biochemistry, University of California, San Diego, La Jolla, California 92093, United States d Univ. Grenoble Alpes, LCBM/PMB and CEA, IRTSV/CBM/PMB and CNRS, LCBM UMR 5249, PMB 38000 Grenoble, France
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عنوان ژورنال:
دوره 8 شماره
صفحات -
تاریخ انتشار 2017